Concept:
We can use Pen Tool effectively for complex selections.
This tutorial teaches basic type of selection that is not very accurate
but gives an idea how to use pen tool for selecting object. We create
the path with Pen Tool and then convert the path into selection.
1. Open Photoshop. Open Image to work with Pen Tool.

2. Select the first Pen Tool from Tool box.

3. Once you select the tool please turn your attention
to the option bar below menus and select "Paths" (Middle
one shown in the following figure)

4. Start making path using pen tool around the edge
of the image. Close the path by clicking on the first point again.

5. Go to Path palette. If its not open, try
Windows > Path

6. Click on the(third from the left) icon "Load
path as a selection" . The path will get converted into the
selection.
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